The hydroxides of the Group II metals, which may be used in thermochemical water-splitting cycles, have been investigated thermoanalytically. (ii) Carbonates. The thermal stability … Solubility. It describes and explains how the thermal stability of the compounds changes as you go down the Group. 3. Small highly charged positive ions distort the electron cloud of the anion. Group 1 compounds tend to be more thermally stable than group 2 compounds because the cation has a smaller charge and a larger ionic radius, and so a lower polarising power. Group 2 Salts - Solubility & Tests (7:27) Thermal Stability of Group 1/2 Carbonates (8:19) Thermal Stability of Group 1/2 Nitrates (4:38) The larger compounds further down require more heat than the lighter compounds in order to decompose. All the alkaline earth metals form carbonates (MCO 3). It consists of a carbon atom surrounded by three oxygen atom in a trigonal planar arrangement. Stability of oxides decreases down the group. 18. Stability increases down the Group. The Group 2 hydrogencarbonates like calcium hydrogencarbonate are so unstable to heat that they only exist in solution. This trend is explained in terms of the Group II metal ions ability to polarise the anion, the carbonate ion. As we go down the group the stability of metal carbonates increases. So what causes this trend? The term "thermal decomposition" describes splitting up a compound by heating it. MCO 3(s) → MO (s) + CO 2(g) Where M is a Group II element. Hence, more is the stability of oxide formed, less will be stability of carbonates. All the carbonates decompose on heating to give carbon dioxide and the oxide. Thermal stability: * Carbonates are decomposed to carbon dioxide and oxide upon heating. Whereas bicarbonates give carbonate, water and carbon dioxide. Thermal stability. One may also ask, how does the thermal … rihu27 rihu27 Answer: down the group the stability of metellic carbonates imcreass. Stability of carbonates increases down group I (alkali) and group II (alkaline earth) metals. However, carbonate of lithium, when heated, decomposes to form lithium oxide. Asked by Wiki User. Thank you Beryllium carbonate decomposing most easily. The nitrate ion is less polarised and the compound is more stable. The electron cloud of anion is distorted to a lesser extent. (You wouldn't see the oxygen also produced). I know stability increases as you go down group 2, please explain why in language a good A level student can understand. If "X" represents any one of the elements: As you go down the Group, the carbonates have to be heated more strongly before they will decompose So C s 2 C O 3 has the highest thermal stability than the other given carbonates. They both have the same number of electrons is their outer shell, but Calcium is further down the group so I would have thought that Calcium is less thermally stable. The solubility of carbonates in water decreases as the atomic number of the metal ion increases. Going down group II, the ionic radii of cations increases. The Facts The effect of heat on the Group 2 carbonates All the carbonates in this Group undergo thermal decomposition to give the metal oxide and carbon dioxide gas. This is because the cation size increases down the Group, this reduces the charge density and polarising power of cation. The respective TG- and DSC-curves are represented. Wiki User Answered . All of these carbonates are white solids, and the oxides that are produced are also white solids. Since beryllium oxide is high stable, it makes BeCO 3 unstable. A higher temperature is required to decompose Ba(NO 3) 2 as compared to Mg(NO 3) 2. b) lower c) A white solid producing a brown gas and leaving a white solid. Carbonate Structure. Since electropositive character increases from Li to Cs All carbonates and bicarbonate are water soluble and their solubility increases from Li to Cs CHEMICAL PROPERTIES Alkalimetals are highly reactive due to low ionization energy. 2012-08-13 15:58:41. Thermal decomposition of Group II carbonates. Let's use MgCO 3 as an example. The effect of heat on the Group 2 carbonates. Both carbonates and nitrates of Group 2 elements become more thermally stable down the group. In fact, these metals can precipitate from their salt solutions as carbonates.Nitrates: Thermal stabilityNitrates of alkali metals,except LiNO3, decompose on strong heating forming nitrites and oxygen. It describes and explains how the thermal stability of the compounds changes as you go down the Group. Thermal stability of Group II nitrates increases down the This is because the cation size increases down the Group, this reduces the charge density and polarising power of cation. MgCO3 decomposes at 540 C. CaCO3 decomposes at 900 C. SrCO3 decomposes at 1290 C. BaCO3 decomposes at 1360 C. This is because of the increasing size of the cation (ionised metal) as we go down the group. All the carbonates in this group undergo thermal decomposition to the metal oxide and carbon dioxide gas. The Facts The effect of heat on the Group 2 carbonates All the carbonates in this Group undergo thermal decomposition to give the metal oxide and carbon dioxide gas. The carbonate ion has a big ionic radius so it is easily polarized by a small, highly charged cation. Calcium ion also has a smaller radius and so a higher charge density giving it a greater polarising power allowing it to distort the bonding for example,2KNO3 -> 2KNO2 +O2Nitrates of alkaline-earth … Even for hydroxides we have the same observations. BeCO 3 ⇌ BeO + CO 2. MgCO 3(s) MgO(s) + CO 2(g) Thermal decomposition is defined as the use of heat to break down a reactant into more than one product Group 2 carbonates … So the correct order of stability of carbonates of Group IIA is B a C O 3 > S r C O 3 > C a C O 3 > M g C O 3 . Thermal decomposition is the term given to splitting up a compound by heating it. Thermal decomposition is the term given to splitting up a compound by heating it. The thermal stability; of these carbonates increases down the group, i.e., from Be to Ba, BeCO 3 < MgCO 3 < CaCO 3 < SrCO 3 < BaCO 3 BeCO 3 is unstable to the extent that it is stable only in atmosphere of CO 2. (ii) All the alkaline earth metals form oxides of formula MO. * Due to same reason, carbonates of group-1 are more stable than those of group-2. The larger compounds further down require more heat than the lighter compounds in order to decompose. 2) Thermal stability of Group II nitrates increases down the Group. GROUP 2: THERMAL STABILITY OF THE CARBONATES AND NITRATES 1. a) Both barium carbonate and barium oxide (the product) are white. Nitrates of both group 1 and group 2 metals are soluble in water. The stability of the metal carbonates can be related to the reactivity series of metals. 2. Nature of carbonates and bicarbonates: Alkali metal carbonates and bicarbonate stability increases down the group. Thermal stability of carbonates increases in a group as we move from top to bottom and decreases in a period as we move from left to right. Thermal decomposition is the term given to splitting up a compound by heating it. As we go down the group, the carbonates have to be heated more strongly before they will decompose. Explanation: New questions in Chemistry. * … Correct order of stability of group 2a metal carbonates is 1 See answer mohitrathimr4440 is waiting for your help. Top Answer. * Thermal stability of group-1 and group-2 carbonates (also of bicarbonates) increases down the group as the polarizing power of the metal ion decreases. Add your answer and earn points. The thermal stability of the hydrogencarbonates. Also, does thermal stability increase or decrease as you go down group 1 (with explanation please)? In all cases, for a particular set of e.g. The thermal stability of Group II carbonates increases as we descend the group. I undergo less corrosioncompared to iron. It means the stability increases from M g C O 3 to B a C O 3 . Group-2 carbonates are fairly soluble in the solution of CO 2; Thermal Stability. All the carbonates in this group undergo thermal decomposition to the metal oxide and carbon dioxide gas. The nitrate ion is less polarised and the compound is more stable. Also, why does thermal stability increase down Group 2? Beryllium carbonate is unstable and can be kept only in the atmosphere of CO2. Solution for group 1 elements with that of group 2 on the basis of the following:… so, the correct order of thermal stability of given carbonates is: BeCO 3 < MgCO 3 < CaCO 3 < K 2 CO 3 Be, Mg and Ca present in second group and K present in the first group. Thanks in advance x Carbonates of group-2 metals are almost insoluble in water and their solubilities further decrease on moving down the group. Charge Density and Polarising Power of Group 2 Metal Cations. 1. Upon heating, carbonates decompose into oxide and carbon dioxide ; The thermal stability of group-1 and group-2 carbonates increase down the group. Decomposition temperatures and decomposition enthalpies of the four hydroxides increase with increasing atomic weight of the compounds. To test what you've learned from this lesson- Answer to question 23 the calcium ion has a larger charge (2+) thatn the potassium ion (1+). 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